Information on the most widely used ASTM standards within the materials testing industry
Lithium-Ion Battery Separator Performance Testing Machine | UnitedTest
UnitedTest manufactures professional lithium-ion battery separator testing machines to comprehensively verify the physical, thermal, electrical, and permeability performance of battery separator films for new energy battery production quality control and material R&D.
Lithium-ion battery separators are critical core components inside lithium batteries. Since lithium battery electrolytes adopt organic solvent systems, battery separators require excellent organic solvent resistance. Most industrial separators are produced from high-strength polyolefin thin films — including polyethylene (PE) and polypropylene (PP) — via dry-process or wet-process manufacturing technologies.
The primary function of lithium battery separators is to isolate positive and negative electrodes to prevent internal short circuits, while enabling free lithium ion transmission through uniform microporous structures. Key material properties including thickness uniformity, mechanical strength, air permeability, and thermal stability directly determine the safety, stability, and service life of lithium-ion batteries.
For power battery applications, high-safety composite separator films with thermal dimensional stability and automatic shutdown protection are widely adopted. Additionally, ceramic-coated and organic-coated battery separators feature upgraded puncture resistance and high-temperature heat resistance for enhanced battery safety performance.
To fully qualify battery separator quality, UnitedTest provides all-in-one testing solutions covering all essential performance tests: tensile strength and elongation test, thermal shrinkage test, puncture strength test, air permeability test, porosity test, electric strength test, and ionic conductivity test.
Scope & Application Industry Field
Separators mainly produced from polyolefin resin (dry uniaxial stretching, dry biaxial stretching, wet biaxial stretching three categories).
Consumer lithium batteries (mobile phones, laptops, wearables)
Power lithium batteries (new energy vehicles, two-wheel electric vehicles)
Energy storage lithium batteries (grid energy storage, household energy storage)
Separator raw material factories, battery cell manufacturing plants, third-party testing laboratories, quality supervision institutions.
General List of Main test for the Polyolefin Separator for Lithium-ion Battery
| Physical Mechanical Properties | |
| Tensile strength & elongation test | Film tensile (250 mm/min, 15‑mm Type‑2 fixture, 0.01 N res); Follow ISO 527-3. |
| Thermal shrink | Forced‑air oven, filter‑paper jig, 90/120 °C programs |
| Puncture Strength | Puncture test fixture with univeral testing machine, Φ1 mm / R0.5 needle, 10‑mm fixture |
| Air Permeability (Gurley‑method) | Time for 100 mL air to pass through 6.45 cm² area under 1.21 kPa at ambient temp/RH. |
| Porosity | Balance + thickness + areal calc (software side) |
| Electrical Properties | |
| Electric strength | 50‑point electrode BDV tester (film version) |
| Ionic conductivity | Jig + EIS integration (layers 1–4, auto regression) |

A lithium battery separator is an ultra-thin plastic film with uniform micropores (usually only a few microns to tens of microns thick). It basically does three main things:
Insulation and separation: Like a 'firewall,' it keeps the positive and negative electrodes apart, preventing short circuits from direct contact.
Ion conduction: The micropores act like 'channels,' allowing lithium ions to move smoothly between the electrodes during charging and discharging.
Safety protection: At high temperatures (usually 120-160°C), the micropores automatically close, cutting off ion transport and preventing thermal runaway, making it a true 'lifesaver' for lithium batteries.
Details introduction of test for Polyolefin Separator for Lithium-ion Battery
| 1, Tensile Strength & Elongation at Break | |
| Test Equipment | UnitedTest Universal tensile testing machine, adjustable test speed 250 mm/min, fixture initial distance 100 mm. Long travel extensometer. |
| Test Specimen info | Type 2 specimen, width (15±0.1) mm; mark MD (longitudinal) & TD (transverse) separately, prepare multiple MD/TD strips. |
| Test Procedure | Condition samples 4h; clamp specimen with 100 mm gauge length; Set test speed (250±10) mm/min, pull until rupture; Record maximum tensile force and elongation at break, convert to tensile strength (MPa). |
| Test requirement | Dry uniaxial: MD ≥ 110 MPa, TD ≥ 10 MPa; elongation MD ≥ 80 %, TD ≥ 10 % Dry biaxial: MD/TD ≥ 100 / 25 MPa; elong MD ≥ 20 %, TD ≥ 80 % Wet biaxial: MD/TD ≥ 100 / 60 MPa; both ≥ 50 % |
| 2, Thermal Shrinkage Test | |
| Test Equipment | Forced air convection oven (temperature accuracy ±1°C); Stainless steel flat plate, quantitative filter paper. |
| Test Specimen info | 3 square specimens of 100 mm × 100 mm; if separator width <100 mm, sample size =100 mm × film width. Mark MD & TD on each sample. |
| Test Procedure | Measure original MD & TD length of conditioned samples; Preheat oven to target temperature (90±1°C or 120±1°C); lay sample between two filter papers on stainless plate inside oven; Keep constant temperature for specified time (2h±12min / 1h±6min); Cool sample to room temperature, re-measure length, calculate shrinkage rate average of 3 samples. |
| Test requirement | 90 °C × 2 h → MD ≤ 4 %, TD varies (dry uniaxial ≤ 0.5 %, dry biaxial ≤ 2 %, wet ≤ 2.5 %) 120 °C × 1 h → dry uniaxial MD ≤ 6 / TD ≤ 1; dry & wet biaxial ≤ 5 / ≤ 13 |
| 3, Puncture Strength Test | |
| Test Equipment | Universal Tester with load cell resolution 0.01 N Puncture fixture with needle: Φ1.0 mm, spherical tip R=0.5 mm Sample fixture with inner diameter 10 mm.
|
| Test Procedure | Clamp flat separator tightly in fixture; Set test speed (100±10) mm/min, lower needle to pierce sample; record peak puncture force \(F_0\); Measure thickness at 4 positions around the puncture hole to get average thickness; Calculate normalized puncture strength per micron thickness. |
| Test requirement | Dry separator: ≥0.133 N/μm Wet separator: ≥0.204 N/μm |
| 4, Air Permeability Test | |
| Test Equipment | Separator air permeability tester, fixed test area 6.45 cm², constant 1.21 kPa differential pressure. |
| Test Specimen | 3 specimens, longitudinal interval 150 mm; size 100×100 mm if film width ≥100 mm; else 100 mm × film width. |
| Test Procedure | Mount conditioned sample on test head, run test, record air passing time, take average of 3 specimens. |
| Test requirement | Index unit: s/100mL; acceptance value subject to customer detailed specification. Definition: Time for 100 mL air passing through 6.45 cm² film under 1.21 kPa pressure. |
| 5, Porosity Test | |
| Test Specimen | 3 specimens same size as air permeability test (100×100 mm or 100 mm × film width). |
| Test Equipment | Analytical balance (resolution 0.0001 g); Thickness gauge, length/width caliper |
| Test Procedure | Measure sample length, width, multi-point thickness to get average d; weigh sample mass m; Input PP/PE raw material true density p0 into formula to compute porosity percentage. |
| 6, Electrical Strength (Dielectric Breakdown Strength) | |
| Test Equipment | 50-point electrical strength breakdown tester for insulating film. |
| Test Specimen info | Large flat separator sheet covering full 50-point electrode area. |
| Test Procedure | Place conditioned separator on electrode platform, execute 50-point breakdown voltage test, calculate average & minimum V/μm value. |
| Test requirement | Minimum electrical strength ≥30 V/μm Average electrical strength ≥50 V/μm Test standard basis: IEC 60674-2, 50-point electrode method |
| 7, Ionic Conductivity Test | |
| Test Equipment | AC impedance EIS test system Sealed test mould, electrolyte: 1.0 mol/L LiPF6 (EC:EMC:DMC=1:1:1 volume ratio) |
| Test Specimen info | 4 identical separator sheets matching resistance mould size. |
| Test Procedure | Immerse 4 separator layers in electrolyte, seal & soak 2 hours fully saturated; Test impedance of 1/2/3/4 layers separately; plot impedance-layer fitting curve; If linear fitting coefficient >0.99, extract single-layer resistance R to compute ionic conductivity; re-test if fitting <0.99. |
Why the test/inspection is Critical for Polyolefin Separator Materials?
Lithium battery separator is the core safety component: it separates anode and cathode, blocks electronic short-circuit, and allows lithium ion passage. Non-standard tested separators will cause battery swelling, short circuit, thermal runaway, fire or explosion.
Unified Quality Benchmark: Eliminates inconsistent testing standards between separator suppliers and battery manufacturers, standardizes acceptance indicators.
Safety Risk Control: Strictly limits thermal shrinkage, puncture resistance, electrical strength to prevent internal short-circuit caused by high temperature or dendrite piercing.
Performance Consistency Guarantee: Standardizes thickness, width, porosity, air permeability to stabilize battery rate discharge, cycle life and energy density.
Regulatory & Inspection Basis: National quality supervision, factory outgoing inspection, type testing all rely on this standard for compliance judgment.
Industry Upgrading Guide: Defines technical thresholds for dry/wet separators, guides R&D of high-safety coated separators.
Keywords: UnitedTest battery separator testing machine, lithium ion battery separator performance tester, polyolefin film battery test equipment, battery safety performance testing machine, dry wet process PE PP battery separator tensile elongation test, ceramic coated battery separator puncture resistance tester, lithium battery separator thermal shrinkage testing equipment, battery film air permeability and porosity analyzer, ionic conductivity and electric strength test for battery separators, power battery composite film thermal stability tester
Related products and device
Related Standard
ISO 527-3 Plastics - TENSILE PROPERTIES - PART 3: FOR FILMS AND SHEETS
ISO 527-3 specifies the test conditions for determining the tensile properties of plastic films and sheets with a thickness less than 1 mm, based on the general principles of ISO 527-1. Provides standardized procedures to measure critical mechanical parameters including tensile strength, yield strength, elongation at break, and Young's modulus for thin plastic materials. It is critically important because thin films behave very differently under stress compared to rigid plastics; they are more prone to tearing, slipping, and deformation. By standardizing the test conditions, this document ensures that material specifications, quality control, and research data are globally comparable and reliable. Specimen created following ISO 527-3 can be used to determine the tensile properties of thin plastic sheets and films including the tensile modulus of elasticity and the tensile energy to break (TEB).
ISO 5636-5 permeability test Paper and board — Determination of air permeance (medium range) Part 5: Gurley method
ISO 5636-5 specifies the Gurley method for determining the air permeance of paper and board using an air resistance tester, the Gurley apparatus.
It is applicable to papers and boards which have air permeances between 0,1 µm/(Pa⋅s) and 100 µm/(Pa⋅s) when tested with the Gurley apparatus. It is unsuitable for rough-surfaced materials, which cannot be securely clamped to avoid leakage.
ISO 15105-1 Plastics — Film and Sheeting — Determination of Gas-transmission Rate — Part 1: Differential-pressure Methods
ISO 15105-1 defines two standardized differential-pressure test methods to quantify the gas barrier performance of plastic films, sheets and multi-layer plastic structures, focusing on measuring Gas Transmission Rate (GTR) and Gas Permeability Coefficient (P) under a controlled gas partial pressure difference across the specimen.
ASTM D5748 determine the resistance of stretch wrap / stretch film to penetration by a probe under a controlled, low-rate (quasi-static) single-velocity condition, while the film is clamped so it develops biaxial stress — the stress state most representative of real-world end use.
ASTM D1434 Standard Test Method for Determining Gas Permeability Characteristics of Plastic Film and Sheeting
ASTM D1434 defines an electronic manometric differential-pressure method to measure three core barrier metrics: Gas Transmission Rate (GTR), permeance, and material permeability (only valid for homogeneous plastics). It covers plastic films, sheets, multi-layer laminates, plastic-coated paper and plastic-coated fabrics, and follows WTO TBT international standardization principles.
ISO 14616 — Plastics – Heatshrinkable films of polyethylene, ethylene copolymers and their mixtures – Determination of shrinkage stress and contraction stress
ISO 14616 quantify two core mechanical properties of PE-based heat-shrink films: shrinking stress (hot shrink stress) and contraction stress (cold clamping stress). It also allows auxiliary measurement of shrinkage ratio for quick comparative evaluation, though it is not the reference method for shrinkage ratio testing.
ISO 11501 Plastics — Film and sheeting — Determination of dimensional change on heating
ISO 11501 specifies a uniform laboratory test method to quantify thermal dimensional variation of plastic films and thin sheets (max thickness 1 mm), covering both machine (longitudinal) and transverse directions, for all plastics whether heat-shrinkable or non-shrink grade.
ASTM D1204 Standard Test Method for Linear Dimensional Changes of Nonrigid Thermoplastic Sheeting or Film at Elevated Temperature
ASTM D1204 is method to measure linear dimensional change (shrinkage or expansion) of nonrigid thermoplastic sheeting/film when exposed to a specified elevated temperature and time in air. Applies to nonrigid thermoplastic sheeting/film made by calender or extrusion processes, the heating medium is air (mechanical convection oven) — this points is the fundamental difference from ASTM D2732 (liquid bath).
ASTM D2732 standardized laboratory method to measure the degree of unrestrained (free) linear thermal shrinkage of plastic films and sheets ≤ 0.76 mm (0.030 in.) thick at a specified temperature. Quantifies irreversible rapid linear dimensional reduction when plastic film is exposed to high temperature under zero or minimal external restraint.
< Previous: None
Require More Customized Solutions?