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Detail Test Guide of Polyolefin Separator for Lithium-ion Battery

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Lithium-Ion Battery Separator Performance Testing Machine | UnitedTest

UnitedTest manufactures professional lithium-ion battery separator testing machines to comprehensively verify the physical, thermal, electrical, and permeability performance of battery separator films for new energy battery production quality control and material R&D.


Lithium-ion battery separators are critical core components inside lithium batteries. Since lithium battery electrolytes adopt organic solvent systems, battery separators require excellent organic solvent resistance. Most industrial separators are produced from high-strength polyolefin thin films — including polyethylene (PE) and polypropylene (PP) — via dry-process or wet-process manufacturing technologies.

The primary function of lithium battery separators is to isolate positive and negative electrodes to prevent internal short circuits, while enabling free lithium ion transmission through uniform microporous structures. Key material properties including thickness uniformity, mechanical strength, air permeability, and thermal stability directly determine the safety, stability, and service life of lithium-ion batteries.

For power battery applications, high-safety composite separator films with thermal dimensional stability and automatic shutdown protection are widely adopted. Additionally, ceramic-coated and organic-coated battery separators feature upgraded puncture resistance and high-temperature heat resistance for enhanced battery safety performance.


To fully qualify battery separator quality, UnitedTest provides all-in-one testing solutions covering all essential performance tests: tensile strength and elongation test, thermal shrinkage test, puncture strength test, air permeability test, porosity test, electric strength test, and ionic conductivity test. 


Scope & Application Industry Field

Separators mainly produced from polyolefin resin (dry uniaxial stretching, dry biaxial stretching, wet biaxial stretching three categories).

Consumer lithium batteries (mobile phones, laptops, wearables)

Power lithium batteries (new energy vehicles, two-wheel electric vehicles)

Energy storage lithium batteries (grid energy storage, household energy storage)

Separator raw material factories, battery cell manufacturing plants, third-party testing laboratories, quality supervision institutions.


General List of Main test for the Polyolefin Separator for Lithium-ion Battery

Physical Mechanical Properties
Tensile strength & elongation test

Film tensile (250 mm/min, 15‑mm Type‑2 fixture, 0.01 N res);  Follow ISO 527-3. 

Thermal shrinkForced‑air oven, filter‑paper jig, 90/120 °C programs
Puncture StrengthPuncture test fixture with univeral testing machine, Φ1 mm / R0.5 needle, 10‑mm fixture
Air Permeability (Gurley‑method)Time for 100 mL air to pass through 6.45 cm² area under 1.21 kPa at ambient temp/RH.
PorosityBalance + thickness + areal calc (software side)
Electrical Properties
Electric strength50‑point electrode BDV tester (film version)
Ionic conductivityJig + EIS integration (layers 1–4, auto regression)

Detail Test Guide of Polyolefin Separator for Lithium-ion Battery

A lithium battery separator is an ultra-thin plastic film with uniform micropores (usually only a few microns to tens of microns thick). It basically does three main things:  

Insulation and separation: Like a 'firewall,' it keeps the positive and negative electrodes apart, preventing short circuits from direct contact.  

Ion conduction: The micropores act like 'channels,' allowing lithium ions to move smoothly between the electrodes during charging and discharging.  

Safety protection: At high temperatures (usually 120-160°C), the micropores automatically close, cutting off ion transport and preventing thermal runaway, making it a true 'lifesaver' for lithium batteries.


Details introduction of test for Polyolefin Separator for Lithium-ion Battery

1, Tensile Strength & Elongation at Break
Test Equipment

UnitedTest Universal tensile testing machine, adjustable test speed 250 mm/min, fixture initial distance 100 mm.

Long travel extensometer. 

Test Specimen infoType 2 specimen, width (15±0.1) mm; mark MD (longitudinal) & TD (transverse) separately, prepare multiple MD/TD strips.
Test ProcedureCondition samples 4h; clamp specimen with 100 mm gauge length;

Set test speed (250±10) mm/min, pull until rupture;

Record maximum tensile force and elongation at break, convert to tensile strength (MPa).

Test requirement

Dry uniaxial: MD ≥ 110 MPa, TD ≥ 10 MPa; elongation MD ≥ 80 %, TD ≥ 10 %

Dry biaxial: MD/TD ≥ 100 / 25 MPa; elong MD ≥ 20 %, TD ≥ 80 %

Wet biaxial: MD/TD ≥ 100 / 60 MPa; both ≥ 50 %

2, Thermal Shrinkage Test
Test Equipment

Forced air convection oven (temperature accuracy ±1°C); Stainless steel flat plate, quantitative filter paper. 

Test Specimen info3 square specimens of 100 mm × 100 mm; if separator width <100 mm, sample size =100 mm × film width. Mark MD & TD on each sample.
Test Procedure

Measure original MD & TD length of conditioned samples;

Preheat oven to target temperature (90±1°C or 120±1°C); lay sample between two filter papers on stainless plate inside oven;

Keep constant temperature for specified time (2h±12min / 1h±6min);

Cool sample to room temperature, re-measure length, calculate shrinkage rate average of 3 samples.

Test requirement

90 °C × 2 h → MD ≤ 4 %, TD varies (dry uniaxial ≤ 0.5 %, dry biaxial ≤ 2 %, wet ≤ 2.5 %)

120 °C × 1 h → dry uniaxial MD ≤ 6 / TD ≤ 1; dry & wet biaxial ≤ 5 / ≤ 13

3, Puncture Strength Test
Test Equipment

Universal Tester with load cell resolution 0.01 N

Puncture fixture with needle: Φ1.0 mm, spherical tip R=0.5 mm

Sample fixture with inner diameter 10 mm.

Detail Test Guide of Polyolefin Separator for Lithium-ion Battery

Test Procedure

Clamp flat separator tightly in fixture;

Set test speed (100±10) mm/min, lower needle to pierce sample; record peak puncture force \(F_0\);

Measure thickness at 4 positions around the puncture hole to get average thickness;

Calculate normalized puncture strength per micron thickness.

Test requirement

Dry separator: ≥0.133 N/μm

Wet separator: ≥0.204 N/μm

4, Air Permeability Test
Test EquipmentSeparator air permeability tester, fixed test area 6.45 cm², constant 1.21 kPa differential pressure.
Test Specimen3 specimens, longitudinal interval 150 mm; size 100×100 mm if film width ≥100 mm; else 100 mm × film width.
Test ProcedureMount conditioned sample on test head, run test, record air passing time, take average of 3 specimens.
Test requirementIndex unit: s/100mL; acceptance value subject to customer detailed specification. Definition: Time for 100 mL air passing through 6.45 cm² film under 1.21 kPa pressure.
5, Porosity Test
Test Specimen3 specimens same size as air permeability test (100×100 mm or 100 mm × film width).
Test Equipment

Analytical balance (resolution 0.0001 g); Thickness gauge, length/width caliper

Test Procedure

Measure sample length, width, multi-point thickness to get average d; weigh sample mass m;

Input PP/PE raw material true density p0 into formula to compute porosity percentage.

6, Electrical Strength (Dielectric Breakdown Strength)
Test Equipment50-point electrical strength breakdown tester for insulating film.
Test Specimen infoLarge flat separator sheet covering full 50-point electrode area.
Test ProcedurePlace conditioned separator on electrode platform, execute 50-point breakdown voltage test, calculate average & minimum V/μm value.
Test requirement

Minimum electrical strength ≥30 V/μm

Average electrical strength ≥50 V/μm

Test standard basis: IEC 60674-2, 50-point electrode method

7, Ionic Conductivity Test
Test Equipment

AC impedance EIS test system

Sealed test mould, electrolyte: 1.0 mol/L LiPF6 (EC:EMC:DMC=1:1:1 volume ratio)

Test Specimen info4 identical separator sheets matching resistance mould size.
Test Procedure

Immerse 4 separator layers in electrolyte, seal & soak 2 hours fully saturated;

Test impedance of 1/2/3/4 layers separately; plot impedance-layer fitting curve;

If linear fitting coefficient >0.99, extract single-layer resistance R to compute ionic conductivity; re-test if fitting <0.99.


Why the test/inspection is Critical for Polyolefin Separator Materials? 

Lithium battery separator is the core safety component: it separates anode and cathode, blocks electronic short-circuit, and allows lithium ion passage. Non-standard tested separators will cause battery swelling, short circuit, thermal runaway, fire or explosion. 

Unified Quality Benchmark: Eliminates inconsistent testing standards between separator suppliers and battery manufacturers, standardizes acceptance indicators.

Safety Risk Control: Strictly limits thermal shrinkage, puncture resistance, electrical strength to prevent internal short-circuit caused by high temperature or dendrite piercing.

Performance Consistency Guarantee: Standardizes thickness, width, porosity, air permeability to stabilize battery rate discharge, cycle life and energy density.

Regulatory & Inspection Basis: National quality supervision, factory outgoing inspection, type testing all rely on this standard for compliance judgment.

Industry Upgrading Guide: Defines technical thresholds for dry/wet separators, guides R&D of high-safety coated separators.


Keywords: UnitedTest battery separator testing machine, lithium ion battery separator performance tester, polyolefin film battery test equipment, battery safety performance testing machine, dry wet process PE PP battery separator tensile elongation test, ceramic coated battery separator puncture resistance tester, lithium battery separator thermal shrinkage testing equipment, battery film air permeability and porosity analyzer, ionic conductivity and electric strength test for battery separators, power battery composite film thermal stability tester


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