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ASTM D2863 Oxygen Index Test — LOI Testing for Plastics, Rubber, Foam & Film

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ASTM D2863 Oxygen Index Tester | Limiting Oxygen Index LOI Test | UnitedTest

ASTM D2863 standard determines plastic limiting oxygen index (LOI / OI), the minimum oxygen volume percentage required to sustain candle-like flaming combustion at ambient temperature. UnitedTest manufactures ASTM D2863 compliant oxygen index testers for polymer flame retardancy and fire safety testing.


ASTM D2863 is the widely adopted standard test method for measuring the minimum oxygen concentration needed to maintain candle-like flaming combustion of plastics, commonly known as Oxygen Index (OI) or Limiting Oxygen Index (LOI). The test calculates the minimum volume percent of oxygen within an oxygen‑nitrogen gas blend that can support steady flaming combustion of a specimen conditioned at 23 ± 2 °C. Simply put, this test evaluates how much oxygen plastic materials require to keep burning continuously.


A core benchmark for material evaluation: regular ambient air holds approximately 21% oxygen. If the measured OI ≤ 21%, the material will sustain combustion under normal air conditions; if OI > 21%, the material is self-extinguishing in ambient air, and a higher OI value represents stronger flame-retardant performance. This test is extensively used for flame retardant material R&D, quality control, fire classification and certification of polymers, plastics, rubber and composite materials. UnitedTest designs and produces high-precision ASTM D2863 oxygen index testing machines for material laboratories and industrial quality inspection.


Test principle

The test measures the minimum volume percentage of oxygen in a flowing oxygen-nitrogen mixture that will just sustain flaming combustion of a vertically oriented specimen. The principle is based on the observation that combustion requires a certain minimum oxygen concentration; below this threshold, the flame cannot propagate and will extinguish. By systematically varying the oxygen concentration and observing burning behavior, the critical oxygen level (oxygen index) is determined.

The oxygen index is calculated as:  OI = [O₂ / (O₂ + N₂)] × 100%

where O₂ and N₂ represent the volumetric flow rates of oxygen and nitrogen, respectively.


Test Methods (Three Procedures)

Procedure A – Top Surface Ignition

- Ignition is applied only to the top surface of the specimen

- The flame is applied to the top edge until the entire top surface is burning

- Used for most rigid, self-supporting materials

- Most commonly used procedure for general flammability ranking


Procedure B – Propagating Ignition

- The flame is applied to the side of the specimen near the top

- Allows flame to propagate downward along the specimen

- Used when evaluating materials where flame spread is a primary concern

- More stringent ignition condition than Procedure A


Procedure C – Short Procedure (Pass/Fail)

- A simplified screening test

- Specimen is tested at a single specified oxygen concentration

- Determines whether the material meets or exceeds a minimum oxygen index requirement

- Used for quality control and compliance verification where a specific threshold must be met


Test Specimen Information

TypeLength (mm)Width (mm)Thickness (mm)Material Form
I80–15010 ± 0.54 ± 0.25Molded materials (bars)
II80–1506.5 ± 0.53.0 ± 0.5General purpose bars
III80–1506.5 ± 0.51.5 ± 0.15Thin rigid sheets
IV140–15052 ± 0.5≤ 10.5Thick sheets/boards
V140–15020 ± 0.5≤ 10.5Cellular materials (foam)
VI80–15020 ± 0.50.02–0.5Flexible films and sheets


Test equipment required for ASTM D2863 Oxygen Index Test

Recommend UntiedTest YZS series Oxygen Index Tester/Limiting Oxygen Index (LOI) Test Machine, consist of below:

Combustion Column

Vertical, heat-resistant quartz glass cylinder

Standard dimensions: ~75 mm inner diameter, ~450 mm height

Glass beads (≈4.5 mm diameter) at the bottom to ensure uniform gas mixing

Gas inlet at the bottom, open at the top

ASTM D2863 Oxygen Index Test — LOI Testing for Plastics, Rubber, Foam

Gas Control and Measurement System

Separate oxygen and nitrogen supply lines (purity ≥ 98%)

Precision mass flow controllers or rotameters for each gas

Pressure gauges and needle valves for flow regulation

Oxygen concentration measurement resolution: ±0.1%

Typical flow rate range: 1.0–15.0 L/min per gas

Specimen Holder

Clamp assembly positioned centrally in the column

Two sets of clamps: one for rigid self-supporting materials, one for flexible films/sheets

Holds specimen vertically with top end at specified height

Ignition System

Handheld propane burner with 2.0 mm diameter copper tube nozzle

Flame length adjustable to 16 ± 4 mm

Electronic ignition option available on modern instruments


Key Test Parameters

Specimen orientationVertical, centred in chimney
Gas mixtureOxygen + nitrogen, flowing upward
Gas velocity40 ± 2 mm/s at 23 ± 2 °C
O₂ measurement accuracy± 0.5 % by volume
O₂ adjustment precision± 0.1 % by volume
Gas temperature23 ± 2 °C entering the chimney
Apparatus ambient23 ± 5 °C
Conditioning≥ 40 h at 23 ± 2 °C and 50 ± 5 % RH per Practice D618; test within 30 min of removal from the conditioning enclosure
Ignition timeUp to 30 s maximum (igniter withdrawn every 5 s to check for sustained burning)
Igniter flame height16 ± 4 mm
Burning-time criterion180 s
Burnt-length criterion50 mm from the ignited end
Concentration step (d)Typically 0.2 %

1. Gas flow stabilization: The gas mixture must flow for at least 30 seconds before ignition to stabilize concentration

2. Ignition technique: Flame applied without disturbing gas flow; burner removed promptly after ignition

3. Burning criteria: A specimen is considered to "burn" if it sustains flaming for at least 3 minutes or burns past the 50 mm mark


Test procedure of ASTM D2863 Oxygen Index Test

  1. Prepare specimens — cut/mold to the specified type and dimensions; mark reference lines per the chosen procedure.

  2. Condition — ≥ 40 h at 23 ± 2 °C, 50 ± 5 % RH.

  3. Calibrate the gas measurement/control system.

  4. Install the specimen vertically in the holder at the chimney centre.

  5. Set gas flow — adjust oxygen/nitrogen to the target concentration at 40 ± 2 mm/s.

  6. Ignite the top of the specimen with the standard flame (≤ 30 s).

  7. Observe — record whether burning exceeds 180 s or the 50 mm mark (X or O).

  8. Adjust — lower O₂ if "X", raise O₂ if "O", by the step size d.

  9. Repeat across a series of specimens until the up-and-down sequence is complete.

  10. Calculate OI via Dixon's up-and-down formula (OI = C_F + k·d) and estimate the standard deviation.


Industry Application Fields

Materials covered:

  • Structurally self-supporting vertical bars or sheet up to 10.5 mm thick — solid, laminated, or cellular materials with apparent density > 15 kg/m³

  • Flexible sheet or film tested while vertically supported

  • In some cases, cellular materials with apparent density < 15 kg/m³

Industry sectors:

  • Plastics & polymer compounding — flame-retardancy QC for ABS, PC, PVC, polyolefins, polyamides, polyesters, engineering polymers

  • Wire & cable — insulation and jacketing compounds (PVC, XLPE, PE), LSZH (low-smoke zero-halogen) and fire-resistant cable formulations

  • Electrical & electronics — enclosures and housings where short-circuit/overheat fire risk matters

  • Building & construction — insulation foams (PU, EPS, XPS, polyisocyanurate), profiles, sealants, geomembranes, roofing

  • Transportation interiors — aerospace, rail, automotive, marine

  • Textiles & fibers — technical textiles, protective workwear, upholstery, carpets

  • Films & flexible packaging — polymer films, multi-layer laminates, agricultural films

  • Rubber & elastomers — vulcanized rubber, TPEs, sealing compounds

  • Flame-retardant additive R&D — evaluating brominated, phosphorus, mineral-filler (ATH/MDH), and intumescent systems


Related Test Standard:

ISO 4589-2Plastics - Determination of burning behaviour by oxygen index - Part 2: Ambient-temperature test
ASTM D2863Standard Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics (Oxygen Index)
GB/T 2406.2Plastics.Determination of burning behaviour by oxygen index.Part 2:Ambient-temperature test
GB/T 5454Textiles--Burning behaviour--Oxygen index method
ISO 4589-3Plastics - Determination of burning behaviour by oxygen index - Part 3: Elevated-temperature test
GB/T 2406.3Plastics—Determination of burning behaviour by oxygen index—Part 3: Elevated-temperature test
IEC 61144Test method for the determination of oxygen index of insulating liquids
GB/T 16581Test method for the determination of oxygen index of insulating liquids
ISO 3582Horizontal flammability test for flexible cellular polymers
NES 714 Commonly used alongside for LOI determination (UK Naval Engineering Standard)


Why ASTM D2863 Oxygen Index Test is Important for Polymeric Materials

It converts "flame retardancy" into a single, objective, quantitative number. Rather than a subjective description, you get one reproducible figure (e.g., OI = 26.8) that can be tracked, specified, and audited.

The 21 % threshold is physically meaningful. Because air is ~21 % oxygen, the OI directly answers the practical question: will this material sustain a flame in a real room? This makes it uniquely intuitive for specification writing.

It is fast, cheap, and uses tiny specimens. It is described as the most economical and precise quality-control test for combustible materials available to modern labs. This makes it ideal for high-volume batch QC and rapid R&D iteration.

It is highly sensitive to flame-retardant formulation. It is the primary tool for screening flame-retardant additives and optimising loading levels during compound development — you can see the effect of adding, say, mineral filler ATH/MDH or a phosphorus FR within a couple of percentage points.

It enables reliable comparative ranking. Different polymers, grades, or formulations can be ranked by flammability on a common scale, guiding material selection.

It feeds regulatory, safety, and certification pathways. Widely used for building-code, aerospace, rail, marine, and electrical-product flame-retardancy compliance.


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Related products and device

ASTM D2863 oxygen index tester, plastic flammability tester

ISO 4589‑2 LOI test apparatus is widely used for flammability testing of plastics, polymer compounds, rubber, rigid & flexible foam materials, cable‑insulation materials, composite laminates, thin packaging films, automotive‑interior plastics, building‑decorative polymer materials, E&E component plastics.

ASTM D2863 flame retardant material testing instrument

Oxygen Index Apparatus/LOI tester (Limitation Oxygen Index tester) is widely used to measure burning performance of plastics, rubber, fiber, foam,,film etc., The technique measures the minimum percentage of oxygen in the test atmosphere that is required to marginally support combustion.

ASTM D2863 flammability test instrument

High-temperature limit oxygen index tester refers to the volume fraction concentration of oxygen that can support the combustion of materials in a mixture of oxygen and nitrogen gas, and is an index that characterizes the combustion behavior of materials.

Related Standard

ISO 4589-2 Plastics burning oxygen index test - LOI Test –

ISO 4589-2 Plastics — Determination of burning behaviour by oxygen index — Part 2: Ambient-temperature test


ISO 4589-2 defines how to measure the oxygen index (OI) — the minimum volume fraction of oxygen, in admixture with nitrogen, that will just support flaming combustion of a small vertical test specimen under specified conditions, at ambient temperature (23 °C ± 2 °C). Results are expressed as a percentage, e.g. OI = 29,5 %.

It covers self‑supporting vertical bars/sheets up to 10,5 mm thick (solid, laminated or cellular materials with apparent density ≥ 100 kg/m³, and possibly some below that), plus a method for flexible sheet/film tested while vertically supported. It also gives a short procedure to check compliance with a specified minimum OI. Note: it may not work satisfactorily for materials with high thermal shrinkage, e.g. highly oriented thin film.

ISO 4589-3 High Temperature Oxygen Index Test Temperature Index (TI) and Flammability Temperature (FT) –

ISO 4589-3 — Plastics — Determination of burning behaviour by oxygen index — Part 3: Elevated-temperature test. 

ISO 4589-3 defines two core output parameters: Temperature Index (TI) — the minimum oxygen volume fraction sustaining flaming combustion at an elevated test temperature; and Flammability Temperature (FT, Annex A normative method) — the temperature at which a specimen just burns in normal air (20.9 % oxygen).

it takes the classic oxygen-index (OI) test and runs it hot, to answer "how flammable is this plastic when it is already hot?"

ASTM D2863 Oxygen Index Test – Frequently Asked Questions (FAQs)

Q1. What is ASTM D2863?

ASTM D2863 is an ASTM International fire-test-response standard titled "Standard Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics (Oxygen Index)." It is maintained by ASTM Committee D20 on Plastics, Subcommittee D20.30 on Thermal Properties, and has been approved for use by agencies of the U.S. Department of Defense.


Q2. What is the Oxygen Index (OI / LOI)?

The Oxygen Index is the minimum concentration of oxygen, expressed as volume percent, in a flowing mixture of oxygen and nitrogen that will just support flaming combustion of a material initially at 23 ± 2 °C under the conditions of this test method. It is also widely called the Limiting Oxygen Index (LOI).


Q3. Why is the number 21 % so important in this test?

Because ambient air contains approximately 21 % oxygen. That makes the OI directly readable in real-world terms:

  • OI < 21 % — normal air supplies more than enough oxygen; the material will continue to burn once ignited (readily combustible).

  • OI ≈ 21–27 % — marginal / slow-burning; tends to self-extinguish in still air, but the safety margin is thin.

  • OI > 27–28 % — generally regarded as self-extinguishing / genuinely flame-retardant. High-risk sectors such as aerospace and rail often specify OI > 28 %.


Q4. Is OI the same as "fire rating"?

No. OI is a quantitative flammability index, not a fire rating or fire-resistance classification. The standard itself states (§1.7) that it does not incorporate all factors required for fire hazard or fire risk assessment, and (§5.2) that correlation with burning characteristics under actual use conditions is not implied.


Q5. Why is ASTM D2863 important for a material?

Five practical reasons:

  1. It turns flame retardancy into one objective number. Instead of a subjective description, you get a reproducible figure (e.g., OI = 26.8) that can be written into a spec, tracked over time, and audited.

  2. The 21 % benchmark is physically meaningful. It answers the practical question: will this material sustain a flame in a normal room?

  3. It is fast, cheap and uses tiny specimens. It is widely regarded as the most economical and precise quality-control test available for combustible materials — ideal for high-volume batch QC and rapid R&D iteration.

  4. It is highly sensitive to flame-retardant formulation. It is the primary screening tool for FR additives — you can see the effect of changing a mineral filler (ATH/MDH), phosphorus, or intumescent loading within a couple of OI points.

  5. It feeds certification and compliance. LOI data is a foundational input to flame-retardancy compliance programmes in building, cable, aerospace, rail, marine and electrical products.


Q6. Who actually uses OI data?

Plastics and polymer compounders, wire & cable makers (PVC, XLPE, PE, LSZH compounds), electrical/electronics enclosure producers, building-insulation foam makers, rubber and elastomer producers, textile and technical-fabric mills, film and flexible-packaging converters, aerospace/rail/automotive interior suppliers, FR-additive developers, universities and third-party certification labs.


Q7. Can OI alone predict real-fire behaviour?

No. ASTM D2863 measures downward, candle-like burning of one small bar in a quiet chamber — with no external radiant heat, no realistic ventilation, and no accounting for dripping, smoke toxicity or heat-release rate. Real fires, and the codes written for them, care about those things. Use OI to rank and screen, then qualify the final material to the code test that governs your application (UL 94, cone calorimetry, IEC 60332, EN 45545-2, etc.).


Q8. How are flexible and thin films prepared?

  • Type V (flexible sheet): clamped by both vertical edges in a frame carrying reference marks 20 mm and 100 mm below the frame top.

  • Type VI (thin film): insert one corner into the slit of the rolling tool and wind the film around the rod in a 45° spiral, tape the last end while still on the rod, pull the rod out, then cut the roll 20 mm from the top end.


Q9. Can I compare results across different specimen types?

Only with care. The standard restricts comparison: results from Type III, V and VI may be compared only with results from specimens of the same form and thickness.


Q10. How does the step size affect uncertainty?

Maximum OI uncertainty ≈ 0.54 at d = 0.2, and ≈ 0.66 at d = 0.4. Smaller steps give tighter results but require more specimens and time.


Q11. What should a test report include?

OI value; specimen type and dimensions; gas measurement/control device accuracy; procedure used (A, B or C); for Procedure C, the specified minimum OI and whether the material was above or below it; estimated standard deviation and concentration increment if other than 0.2 %; observed behaviour (charring, dripping, severe shrinkage, erratic burning, afterglow); and any deviations from the method.


Q12. What are common causes of scattered or unreliable results?

Inconsistent specimen preparation (dimensional deviation, edge burrs, surface contamination); inadequate conditioning (especially for hygroscopic materials); incorrect gas flow velocity; ignition time too short or too long; specimen not vertical; and operator subjectivity in judging the burn/no-burn response. Dripping that ignites cotton wool below is always recorded and can dominate the result.


Q13. Does specimen thickness change the OI?

Yes, significantly. Thicker specimens dissipate heat less readily and tend to give lower OI; thinner specimens cool faster and tend to give higher OI. Always test at the standard thickness and compare like with like.


Q14. Is ASTM D2863 the same as ISO 4589-2?

They are technically equivalent in principle and apparatus when direct oxygen-concentration measurement (§6.3.1) is used. Both define Procedure A (top surface ignition), Procedure B (propagating ignition) and a short procedure. Watch the details: ASTM D2863 states a cellular-density threshold of 15 kg/m³ (vs 100 kg/m³ in ISO), and there are minor differences in specimen sizes and gas-flow control. Always test to the standard named by your customer or regulation.


Q15. How does ASTM D2863 differ from UL 94?

They are complementary, not interchangeable:


ASTM D2863 (LOI)

UL 94

Result type

Quantitative — a number (e.g. 28 %)

Qualitative — a class (V-0, V-1, V-2, HB)

What it measures

Minimum oxygen needed to sustain combustion

Extinguishing and dripping behaviour in air

Typical use

R&D, formulation screening, QC

Final product certification

A high OI does not guarantee UL 94 V-0, and a V-0 material is not guaranteed a high OI. Published comparisons find only limited, inconsistent correlation between these methods and full-scale fire behaviour. Practically: LOI < 28 % makes V-0 unlikely; LOI ≥ 30 % is a useful screening indicator but not a guarantee.


Q16: Why Choose UnitedTest as Your Oxygen Index Tester Supplier?

UnitedTest – Leading Manufacturer of ASTM D2863 Oxygen Index Test Equipment


UnitedTest is a professional manufacturer and supplier of high-precision **ASTM D2863 oxygen index test equipment**, also known as limiting oxygen index (LOI) testers. With years of expertise in flammability testing instrumentation, UnitedTest designs and produces advanced oxygen index testing machines that fully comply with ASTM D2863, ISO 4589-2, GB/T 2406, and other international standards.

Our oxygen index tester series delivers exceptional accuracy, reliability, and ease of use for plastics testing laboratories, R&D centers, quality control departments, and third-party testing institutions worldwide.


UnitedTest stands out among oxygen index test machine manufacturers for our commitment to quality, precision, and customer support:

  • Expert Technical Support – Our team of flammability testing specialists provides installation guidance, calibration services, and ASTM D2863 standard training

  • Customization Capability – We offer tailored solutions for specific testing requirements, including elevated temperature options and automated testing configurations

  • Global Distribution Network – Fast worldwide shipping with professional on-site installation and training services available

  • Competitive Pricing – Direct factory pricing without compromising on quality or performance

  • Comprehensive After-Sales Service – Warranty coverage, spare parts availability, and ongoing technical assistance

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